ESI-MS Analysis of Thiol-yne Click Reaction in Petroleum Medium
نویسندگان
چکیده
منابع مشابه
Fabrication of Hypericin Imprinted Polymer Nanospheres via Thiol-Yne Click Reaction
To fabricate molecularly imprinted polymer nanospheres via click reaction, five different clickable compounds were synthesized and two types of click reactions (azide-alkyne and thiol-yne) were explored. It was found that molecularly imprinted polymer nanospheres could be successfully synthesized via thiol-yne click reaction using 3,5-diethynyl-pyridine (1) as the monomer, tris(3-mercaptopropio...
متن کاملVisible light mediated metal-free thiol–yne click reaction† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc02132h Click here for additional data file.
The carbon-sulfur bond formation reaction is of paramount importance for functionalized materials design, as well as for biochemical applications. The use of expensive metal-based catalysts and the consequent contamination with trace metal impurities are challenging drawbacks of the existing methodologies. Here, we describe the first environmentally friendly metal-free photoredox pathway to the...
متن کاملFacile Image Patterning via Sequential Thiol−Michael/Thiol−Yne Click Reactions
Freestanding substrates with high refractive index modulation, good oxygen resistance, and low volume shrinkage are critical in photolithography for the purpose of high density data storage, image patterning and anticounterfeiting. Herein, we demonstrate a novel paradigm of direct holographic image patterning via the radical-mediated thiol− yne click reaction subsequent to the base-catalyzed th...
متن کاملSurface glycosylation of polymer membrane by thiol-yne click chemistry for affinity adsorption of lectin.
We present a novel approach to constructing glycosylated surface for microporous membrane. Carbohydrate derivative can be facilely bound onto the alkyne-modified membrane surface via thiol-yne click chemistry. The glycosylated membrane surface shows an excellent affinity adsorption to lectin on the basis of carbohydrate-protein recognition.
متن کاملMulti-molecule reaction of serum albumin can occur through thiol-yne coupling.
The free-radical hydrothiolation of alkynes (thiol-yne coupling, TYC) unites two thiol fragments across the carbon-carbon triple bond to give a dithioether derivative with exclusive 1,2-addition; this reaction can be used for modification of peptides and proteins allowing glycoconjugation and fluorescent labeling. These results have implications not only as a flexible strategy for attaching two...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Molecules
سال: 2021
ISSN: 1420-3049
DOI: 10.3390/molecules26102896